IGGCAS OpenIR  > 岩石圈演化国家重点实验室
High-precision Measurement of Trace Level Na, K, P, S, Cr, and Ni in Lunar Glass Using Electron Probe Microanalysis
Zhang, Di1,2; Chen, Yi1,2; Yang, Wei1; Fournelle, John H.3; Ji, Jianglong1,2; Su, Bin1; Mao, Qian1; Jia, Lihui1; Yuan, Jiangyan1; Li, Xiaoguang1
2022
Source PublicationATOMIC SPECTROSCOPY
ISSN0195-5373
Volume43Issue:1Pages:28-41
AbstractLunar glass can provide critical information on the genesis of lunar rocks and the evolution of the Moon's interior. Several minor and trace elements in lunar glass, such as Na, K, P, S, Cr, and Ni, can be measured by electron probe microanalysis (EPMA) and are informative for understanding glass type, impact volatilization, and magmatic evolution processes. However, the analytical accuracy and precision of these trace-level elements in glass can be impeded by beam sensitivity, peak shift of X-ray and secondary fluorescence effects. Using EPMA, we constructed an optimized analytical method with high accuracy and precision to analyze trace elements simultaneously with major elements in lunar glass. The method was developed using the CAMECA SXFive EPMA at the Institute of Geology and Geophysics, Chinese Academy of Sciences (IGGCAS). The optimal analytical conditions for Na, K, P, S, Cr, and Ni in lunar glass were as follows: 20 kV accelerating voltage, 100 nA beam current, 10 mu m beam diameter, linear background mode, using large-area analytical crystals and aggregate counting strategy and a 10-min total counting time. Replicate analyses on basalt and komatiite glass standards show that the analytical results are consistent with the reference values. Variations in the levels of the analyzed trace elements fall within +/- 10%. The detection limits (3 sigma) for Na, K, P, S, Cr, and Ni can be lowered to 17-96 ppm. Our method can prohibit sample damage of lunar glass even after a 10-min analysis time. Therefore, this optimized method can provide precise trace and major element analysis of lunar glass and help to trace its origin.
DOI10.46770/AS.2022.001
Funding OrganizationKey Research Program of the Chinese Academy of Sciences ; Key Research Program of the Chinese Academy of Sciences ; Key Research Program of the Chinese Academy of Sciences ; Key Research Program of the Chinese Academy of Sciences ; pre-research project on Civil Aerospace Technologies of China National Space Administration ; pre-research project on Civil Aerospace Technologies of China National Space Administration ; pre-research project on Civil Aerospace Technologies of China National Space Administration ; pre-research project on Civil Aerospace Technologies of China National Space Administration ; Key Research Program ; Key Research Program ; Key Research Program ; Key Research Program ; Institute of Geology and Geophysics, Chinese Academy of Sciences ; Institute of Geology and Geophysics, Chinese Academy of Sciences ; Institute of Geology and Geophysics, Chinese Academy of Sciences ; Institute of Geology and Geophysics, Chinese Academy of Sciences ; Key Research Program of the Chinese Academy of Sciences ; Key Research Program of the Chinese Academy of Sciences ; Key Research Program of the Chinese Academy of Sciences ; Key Research Program of the Chinese Academy of Sciences ; pre-research project on Civil Aerospace Technologies of China National Space Administration ; pre-research project on Civil Aerospace Technologies of China National Space Administration ; pre-research project on Civil Aerospace Technologies of China National Space Administration ; pre-research project on Civil Aerospace Technologies of China National Space Administration ; Key Research Program ; Key Research Program ; Key Research Program ; Key Research Program ; Institute of Geology and Geophysics, Chinese Academy of Sciences ; Institute of Geology and Geophysics, Chinese Academy of Sciences ; Institute of Geology and Geophysics, Chinese Academy of Sciences ; Institute of Geology and Geophysics, Chinese Academy of Sciences ; Key Research Program of the Chinese Academy of Sciences ; Key Research Program of the Chinese Academy of Sciences ; Key Research Program of the Chinese Academy of Sciences ; Key Research Program of the Chinese Academy of Sciences ; pre-research project on Civil Aerospace Technologies of China National Space Administration ; pre-research project on Civil Aerospace Technologies of China National Space Administration ; pre-research project on Civil Aerospace Technologies of China National Space Administration ; pre-research project on Civil Aerospace Technologies of China National Space Administration ; Key Research Program ; Key Research Program ; Key Research Program ; Key Research Program ; Institute of Geology and Geophysics, Chinese Academy of Sciences ; Institute of Geology and Geophysics, Chinese Academy of Sciences ; Institute of Geology and Geophysics, Chinese Academy of Sciences ; Institute of Geology and Geophysics, Chinese Academy of Sciences ; Key Research Program of the Chinese Academy of Sciences ; Key Research Program of the Chinese Academy of Sciences ; Key Research Program of the Chinese Academy of Sciences ; Key Research Program of the Chinese Academy of Sciences ; pre-research project on Civil Aerospace Technologies of China National Space Administration ; pre-research project on Civil Aerospace Technologies of China National Space Administration ; pre-research project on Civil Aerospace Technologies of China National Space Administration ; pre-research project on Civil Aerospace Technologies of China National Space Administration ; Key Research Program ; Key Research Program ; Key Research Program ; Key Research Program ; Institute of Geology and Geophysics, Chinese Academy of Sciences ; Institute of Geology and Geophysics, Chinese Academy of Sciences ; Institute of Geology and Geophysics, Chinese Academy of Sciences ; Institute of Geology and Geophysics, Chinese Academy of Sciences
WOS KeywordALKALI-SILICATE-GLASSES ; MICROPROBE ANALYSIS ; OXIDATION-STATE ; SECONDARY FLUORESCENCE ; SULFUR SPECIATION ; VOLCANIC GLASSES ; ELEMENT ANALYSIS ; MELT INCLUSIONS ; IMPACT GLASSES ; CONSTRAINTS
Language英语
Funding ProjectKey Research Program of the Chinese Academy of Sciences[ZDBS-SSW-JSC007-15] ; pre-research project on Civil Aerospace Technologies of China National Space Administration[D020203] ; Key Research Program[IGGCAS-202101] ; Institute of Geology and Geophysics, Chinese Academy of Sciences[11990890]
Funding OrganizationKey Research Program of the Chinese Academy of Sciences ; Key Research Program of the Chinese Academy of Sciences ; Key Research Program of the Chinese Academy of Sciences ; Key Research Program of the Chinese Academy of Sciences ; pre-research project on Civil Aerospace Technologies of China National Space Administration ; pre-research project on Civil Aerospace Technologies of China National Space Administration ; pre-research project on Civil Aerospace Technologies of China National Space Administration ; pre-research project on Civil Aerospace Technologies of China National Space Administration ; Key Research Program ; Key Research Program ; Key Research Program ; Key Research Program ; Institute of Geology and Geophysics, Chinese Academy of Sciences ; Institute of Geology and Geophysics, Chinese Academy of Sciences ; Institute of Geology and Geophysics, Chinese Academy of Sciences ; Institute of Geology and Geophysics, Chinese Academy of Sciences ; Key Research Program of the Chinese Academy of Sciences ; Key Research Program of the Chinese Academy of Sciences ; Key Research Program of the Chinese Academy of Sciences ; Key Research Program of the Chinese Academy of Sciences ; pre-research project on Civil Aerospace Technologies of China National Space Administration ; pre-research project on Civil Aerospace Technologies of China National Space Administration ; pre-research project on Civil Aerospace Technologies of China National Space Administration ; pre-research project on Civil Aerospace Technologies of China National Space Administration ; Key Research Program ; Key Research Program ; Key Research Program ; Key Research Program ; Institute of Geology and Geophysics, Chinese Academy of Sciences ; Institute of Geology and Geophysics, Chinese Academy of Sciences ; Institute of Geology and Geophysics, Chinese Academy of Sciences ; Institute of Geology and Geophysics, Chinese Academy of Sciences ; Key Research Program of the Chinese Academy of Sciences ; Key Research Program of the Chinese Academy of Sciences ; Key Research Program of the Chinese Academy of Sciences ; Key Research Program of the Chinese Academy of Sciences ; pre-research project on Civil Aerospace Technologies of China National Space Administration ; pre-research project on Civil Aerospace Technologies of China National Space Administration ; pre-research project on Civil Aerospace Technologies of China National Space Administration ; pre-research project on Civil Aerospace Technologies of China National Space Administration ; Key Research Program ; Key Research Program ; Key Research Program ; Key Research Program ; Institute of Geology and Geophysics, Chinese Academy of Sciences ; Institute of Geology and Geophysics, Chinese Academy of Sciences ; Institute of Geology and Geophysics, Chinese Academy of Sciences ; Institute of Geology and Geophysics, Chinese Academy of Sciences ; Key Research Program of the Chinese Academy of Sciences ; Key Research Program of the Chinese Academy of Sciences ; Key Research Program of the Chinese Academy of Sciences ; Key Research Program of the Chinese Academy of Sciences ; pre-research project on Civil Aerospace Technologies of China National Space Administration ; pre-research project on Civil Aerospace Technologies of China National Space Administration ; pre-research project on Civil Aerospace Technologies of China National Space Administration ; pre-research project on Civil Aerospace Technologies of China National Space Administration ; Key Research Program ; Key Research Program ; Key Research Program ; Key Research Program ; Institute of Geology and Geophysics, Chinese Academy of Sciences ; Institute of Geology and Geophysics, Chinese Academy of Sciences ; Institute of Geology and Geophysics, Chinese Academy of Sciences ; Institute of Geology and Geophysics, Chinese Academy of Sciences
WOS Research AreaSpectroscopy
WOS SubjectSpectroscopy
WOS IDWOS:000765622700005
PublisherATOMIC SPECTROSCOPY PRESS LTD
Citation statistics
Document Type期刊论文
Identifierhttp://ir.iggcas.ac.cn/handle/132A11/104987
Collection岩石圈演化国家重点实验室
Corresponding AuthorChen, Yi
Affiliation1.Chinese Acad Sci, Inst Geol & Geophys, State Key Lab Lithospher Evolut, Beijing 100029, Peoples R China
2.Univ Chinese Acad Sci, Coll Earth & Planetary Sci, Beijing 100049, Peoples R China
3.Univ Wisconsin, Dept Geosci, Madison, WI 53706 USA
First Author AffilicationState Key Laboratory of Lithospheric Evolution
Corresponding Author AffilicationState Key Laboratory of Lithospheric Evolution
Recommended Citation
GB/T 7714
Zhang, Di,Chen, Yi,Yang, Wei,et al. High-precision Measurement of Trace Level Na, K, P, S, Cr, and Ni in Lunar Glass Using Electron Probe Microanalysis[J]. ATOMIC SPECTROSCOPY,2022,43(1):28-41.
APA Zhang, Di.,Chen, Yi.,Yang, Wei.,Fournelle, John H..,Ji, Jianglong.,...&Li, Xiaoguang.(2022).High-precision Measurement of Trace Level Na, K, P, S, Cr, and Ni in Lunar Glass Using Electron Probe Microanalysis.ATOMIC SPECTROSCOPY,43(1),28-41.
MLA Zhang, Di,et al."High-precision Measurement of Trace Level Na, K, P, S, Cr, and Ni in Lunar Glass Using Electron Probe Microanalysis".ATOMIC SPECTROSCOPY 43.1(2022):28-41.
Files in This Item:
There are no files associated with this item.
Related Services
Recommend this item
Bookmark
Usage statistics
Export to Endnote
Google Scholar
Similar articles in Google Scholar
[Zhang, Di]'s Articles
[Chen, Yi]'s Articles
[Yang, Wei]'s Articles
Baidu academic
Similar articles in Baidu academic
[Zhang, Di]'s Articles
[Chen, Yi]'s Articles
[Yang, Wei]'s Articles
Bing Scholar
Similar articles in Bing Scholar
[Zhang, Di]'s Articles
[Chen, Yi]'s Articles
[Yang, Wei]'s Articles
Terms of Use
No data!
Social Bookmark/Share
Add to CiteULike Add to Connotea Add to Del.icio.us Add to Digg Add to Reddit Add to Technorati
All comments (0)
No comment.
 

Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.