Institutional Repository of Key Laboratory of Mineral Resources, Chinese Academy of Sciences
High-precision copper isotopic analysis using a Nu Sapphire MC-ICP-MS | |
Wang, Jing1![]() | |
2022-10-03 | |
Source Publication | JOURNAL OF ANALYTICAL ATOMIC SPECTROMETRY
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ISSN | 0267-9477 |
Pages | 10 |
Abstract | Here we present an analytical method for Cu isotopic measurement using standard-sample bracketing on a Nu Sapphire multi-collector inductively coupled plasma mass spectrometer. The effects of Cu concentration and HNO3 molarity mismatch between the standard and the sample, as well as the presence of matrix elements have been evaluated. Intermediate precision of better than +/- 0.030 parts per thousand for delta Cu-65 (2SD) was routinely obtained on NIST SRM 3114 and NWU-Cu-A. Accurate measurements were achieved when C-Na/C-Cu < 0.5, C-Ti/C-Cu, C-Fe/C-Cu and C-Co/C-Cu < 1, C-Ni/C-Cu < 3 and C-Zn/C-Cu < 10. High-precision Cu isotopic data were determined for nineteen geological reference materials, including igneous rocks, sedimentary rocks, metamorphic rocks and chalcopyrite, with an overall range of similar to 0.44 parts per thousand (-0.056 parts per thousand to 0.384 parts per thousand), nearly 15 times the current analytical precision. The Cu isotopic data of these reference materials can be used for future interlaboratory comparisons. |
DOI | 10.1039/d2ja00197g |
Funding Organization | Ministry of Science and Technology National Key R&D Program of China ; Ministry of Science and Technology National Key R&D Program of China ; Ministry of Science and Technology National Key R&D Program of China ; Ministry of Science and Technology National Key R&D Program of China ; Youth Innovation Promotion Association, Chinese Academy of Sciences ; Youth Innovation Promotion Association, Chinese Academy of Sciences ; Youth Innovation Promotion Association, Chinese Academy of Sciences ; Youth Innovation Promotion Association, Chinese Academy of Sciences ; Experimental Technology Innovation Fund of the Institute of Geology and Geophysics, Chinese Academy of Sciences ; Experimental Technology Innovation Fund of the Institute of Geology and Geophysics, Chinese Academy of Sciences ; Experimental Technology Innovation Fund of the Institute of Geology and Geophysics, Chinese Academy of Sciences ; Experimental Technology Innovation Fund of the Institute of Geology and Geophysics, Chinese Academy of Sciences ; Ministry of Science and Technology National Key R&D Program of China ; Ministry of Science and Technology National Key R&D Program of China ; Ministry of Science and Technology National Key R&D Program of China ; Ministry of Science and Technology National Key R&D Program of China ; Youth Innovation Promotion Association, Chinese Academy of Sciences ; Youth Innovation Promotion Association, Chinese Academy of Sciences ; Youth Innovation Promotion Association, Chinese Academy of Sciences ; Youth Innovation Promotion Association, Chinese Academy of Sciences ; Experimental Technology Innovation Fund of the Institute of Geology and Geophysics, Chinese Academy of Sciences ; Experimental Technology Innovation Fund of the Institute of Geology and Geophysics, Chinese Academy of Sciences ; Experimental Technology Innovation Fund of the Institute of Geology and Geophysics, Chinese Academy of Sciences ; Experimental Technology Innovation Fund of the Institute of Geology and Geophysics, Chinese Academy of Sciences ; Ministry of Science and Technology National Key R&D Program of China ; Ministry of Science and Technology National Key R&D Program of China ; Ministry of Science and Technology National Key R&D Program of China ; Ministry of Science and Technology National Key R&D Program of China ; Youth Innovation Promotion Association, Chinese Academy of Sciences ; Youth Innovation Promotion Association, Chinese Academy of Sciences ; Youth Innovation Promotion Association, Chinese Academy of Sciences ; Youth Innovation Promotion Association, Chinese Academy of Sciences ; Experimental Technology Innovation Fund of the Institute of Geology and Geophysics, Chinese Academy of Sciences ; Experimental Technology Innovation Fund of the Institute of Geology and Geophysics, Chinese Academy of Sciences ; Experimental Technology Innovation Fund of the Institute of Geology and Geophysics, Chinese Academy of Sciences ; Experimental Technology Innovation Fund of the Institute of Geology and Geophysics, Chinese Academy of Sciences ; Ministry of Science and Technology National Key R&D Program of China ; Ministry of Science and Technology National Key R&D Program of China ; Ministry of Science and Technology National Key R&D Program of China ; Ministry of Science and Technology National Key R&D Program of China ; Youth Innovation Promotion Association, Chinese Academy of Sciences ; Youth Innovation Promotion Association, Chinese Academy of Sciences ; Youth Innovation Promotion Association, Chinese Academy of Sciences ; Youth Innovation Promotion Association, Chinese Academy of Sciences ; Experimental Technology Innovation Fund of the Institute of Geology and Geophysics, Chinese Academy of Sciences ; Experimental Technology Innovation Fund of the Institute of Geology and Geophysics, Chinese Academy of Sciences ; Experimental Technology Innovation Fund of the Institute of Geology and Geophysics, Chinese Academy of Sciences ; Experimental Technology Innovation Fund of the Institute of Geology and Geophysics, Chinese Academy of Sciences |
WOS Keyword | NATURAL VARIATIONS ; CU ; ZINC ; ZN ; FRACTIONATION ; GEOCHEMISTRY ; PURIFICATION ; ABUNDANCE ; RELEVANT ; DEPOSIT |
Language | 英语 |
Funding Project | Ministry of Science and Technology National Key R&D Program of China[2022YFC2903501] ; Youth Innovation Promotion Association, Chinese Academy of Sciences ; Experimental Technology Innovation Fund of the Institute of Geology and Geophysics, Chinese Academy of Sciences[TEC 202103] |
Funding Organization | Ministry of Science and Technology National Key R&D Program of China ; Ministry of Science and Technology National Key R&D Program of China ; Ministry of Science and Technology National Key R&D Program of China ; Ministry of Science and Technology National Key R&D Program of China ; Youth Innovation Promotion Association, Chinese Academy of Sciences ; Youth Innovation Promotion Association, Chinese Academy of Sciences ; Youth Innovation Promotion Association, Chinese Academy of Sciences ; Youth Innovation Promotion Association, Chinese Academy of Sciences ; Experimental Technology Innovation Fund of the Institute of Geology and Geophysics, Chinese Academy of Sciences ; Experimental Technology Innovation Fund of the Institute of Geology and Geophysics, Chinese Academy of Sciences ; Experimental Technology Innovation Fund of the Institute of Geology and Geophysics, Chinese Academy of Sciences ; Experimental Technology Innovation Fund of the Institute of Geology and Geophysics, Chinese Academy of Sciences ; Ministry of Science and Technology National Key R&D Program of China ; Ministry of Science and Technology National Key R&D Program of China ; Ministry of Science and Technology National Key R&D Program of China ; Ministry of Science and Technology National Key R&D Program of China ; Youth Innovation Promotion Association, Chinese Academy of Sciences ; Youth Innovation Promotion Association, Chinese Academy of Sciences ; Youth Innovation Promotion Association, Chinese Academy of Sciences ; Youth Innovation Promotion Association, Chinese Academy of Sciences ; Experimental Technology Innovation Fund of the Institute of Geology and Geophysics, Chinese Academy of Sciences ; Experimental Technology Innovation Fund of the Institute of Geology and Geophysics, Chinese Academy of Sciences ; Experimental Technology Innovation Fund of the Institute of Geology and Geophysics, Chinese Academy of Sciences ; Experimental Technology Innovation Fund of the Institute of Geology and Geophysics, Chinese Academy of Sciences ; Ministry of Science and Technology National Key R&D Program of China ; Ministry of Science and Technology National Key R&D Program of China ; Ministry of Science and Technology National Key R&D Program of China ; Ministry of Science and Technology National Key R&D Program of China ; Youth Innovation Promotion Association, Chinese Academy of Sciences ; Youth Innovation Promotion Association, Chinese Academy of Sciences ; Youth Innovation Promotion Association, Chinese Academy of Sciences ; Youth Innovation Promotion Association, Chinese Academy of Sciences ; Experimental Technology Innovation Fund of the Institute of Geology and Geophysics, Chinese Academy of Sciences ; Experimental Technology Innovation Fund of the Institute of Geology and Geophysics, Chinese Academy of Sciences ; Experimental Technology Innovation Fund of the Institute of Geology and Geophysics, Chinese Academy of Sciences ; Experimental Technology Innovation Fund of the Institute of Geology and Geophysics, Chinese Academy of Sciences ; Ministry of Science and Technology National Key R&D Program of China ; Ministry of Science and Technology National Key R&D Program of China ; Ministry of Science and Technology National Key R&D Program of China ; Ministry of Science and Technology National Key R&D Program of China ; Youth Innovation Promotion Association, Chinese Academy of Sciences ; Youth Innovation Promotion Association, Chinese Academy of Sciences ; Youth Innovation Promotion Association, Chinese Academy of Sciences ; Youth Innovation Promotion Association, Chinese Academy of Sciences ; Experimental Technology Innovation Fund of the Institute of Geology and Geophysics, Chinese Academy of Sciences ; Experimental Technology Innovation Fund of the Institute of Geology and Geophysics, Chinese Academy of Sciences ; Experimental Technology Innovation Fund of the Institute of Geology and Geophysics, Chinese Academy of Sciences ; Experimental Technology Innovation Fund of the Institute of Geology and Geophysics, Chinese Academy of Sciences |
WOS Research Area | Chemistry ; Spectroscopy |
WOS Subject | Chemistry, Analytical ; Spectroscopy |
WOS ID | WOS:000877640200001 |
Publisher | ROYAL SOC CHEMISTRY |
Citation statistics | |
Document Type | 期刊论文 |
Identifier | http://ir.iggcas.ac.cn/handle/132A11/107732 |
Collection | 矿产资源研究院重点实验室 |
Corresponding Author | Wang, Jing; Su, Ben-Xun |
Affiliation | 1.Chinese Acad Sci, Inst Geol & Geophys, Key Lab Mineral Resources, Beijing 100029, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 3.Northwest Univ, Dept Geol, State Key Lab Continental Dynam, Xian 710069, Peoples R China 4.Nu Instruments, Wrexham Ind Estate,Unit 74 Clywedog Rd South, Wrexham LL13 9XS, Wales |
First Author Affilication | Key Laboratory of Mineral Resources, Chinese Academy of Sciences |
Corresponding Author Affilication | Key Laboratory of Mineral Resources, Chinese Academy of Sciences |
Recommended Citation GB/T 7714 | Wang, Jing,Su, Ben-Xun,Tang, Dong-Mei,et al. High-precision copper isotopic analysis using a Nu Sapphire MC-ICP-MS[J]. JOURNAL OF ANALYTICAL ATOMIC SPECTROMETRY,2022:10. |
APA | Wang, Jing.,Su, Ben-Xun.,Tang, Dong-Mei.,Yuan, Qing-Han.,Li, Wen-Jun.,...&Zhao, Ye.(2022).High-precision copper isotopic analysis using a Nu Sapphire MC-ICP-MS.JOURNAL OF ANALYTICAL ATOMIC SPECTROMETRY,10. |
MLA | Wang, Jing,et al."High-precision copper isotopic analysis using a Nu Sapphire MC-ICP-MS".JOURNAL OF ANALYTICAL ATOMIC SPECTROMETRY (2022):10. |
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