Institutional Repository of State Key Laboratory of Lithospheric Evolution
| Thermally induced phase transition of troilite during Micro-Raman spectroscopy analysis | |
| Li, Xiaoguang1; Chen, Yi1; Tang, Xu2; Gu, Lixin2; Yuan, Jiangyan1; Su, Wen1; Tian, Hengci3; Luo, Huiqian4; Cai, Shuhui1; Komarneni, Sridhar5,6 | |
| 2023-01-15 | |
| Source Publication | ICARUS
 |
| ISSN | 0019-1035 |
| Volume | 390Pages:10 |
| Abstract | Troilite is one type of FeS polymorph formed under reducing environmental conditions. However, its phase transition by laser heating during Raman analysis has not been investigated in detail. This study focuses on identifying changes to Raman spectra of troilite resulted by laser heating during Raman analysis so as to determine optimized analytical conditions for characterizing iron sulfides. We comfirm that iron sulfides exposed in air are easily transformed to magnetite and hematite after a high-power laser (> 200 mW/mu m(2) for pyrite and > 14 mW/mu m(2) for troilite) irradiation. Troilite crystal structure is also broken easily by laser (>12 mW/mu m(2)) under the vacuum conditions due to the volatilization of S and Fe, possibly inducing the formation of nanophase metallic iron. Therefore, iron sulfides are expected to be sensitive to laser heating. Here, we have confirmed the laser heating effect through a set of heating experiments from ambient temperature to 500 degrees C with various laser powers. Our results suggest that Raman analysis for troilite should be performed with a low laser power of <1.50 mW (12 mW/mu m(2)) both in air and vacuum environments. The heating effects on troilite phase transition can be responsible for the formation of magnetite, hematite, and nanophase metallic iron in lunar samples. The thermally induced phase transition of troilite observed in this study is important because it undoubtedly modifies both the redox state and magnetic property of extraterrestrial samples and would trigger a misleading interpretation of planetary evolution. |
| Keyword | Troilite Raman spectroscopy Laser irradiation Magnetite Nanophase metallic iron |
| DOI | 10.1016/j.icarus.2022.115299 |
| Funding Organization | Key Research Program of the Chinese Academy of Sciences ; Key Research Program of the Chinese Academy of Sciences ; Key Research Program of the Chinese Academy of Sciences ; Key Research Program of the Chinese Academy of Sciences ; pre-research project on Civil Aerospace Technologies of China National Space Administration ; pre-research project on Civil Aerospace Technologies of China National Space Administration ; pre-research project on Civil Aerospace Technologies of China National Space Administration ; pre-research project on Civil Aerospace Technologies of China National Space Administration ; Key Research Program ; Key Research Program ; Key Research Program ; Key Research Program ; Experimental Technology Innovation Fund of the Institute of Geology and Geophysics, Chinese Academy of Sciences ; Experimental Technology Innovation Fund of the Institute of Geology and Geophysics, Chinese Academy of Sciences ; Experimental Technology Innovation Fund of the Institute of Geology and Geophysics, Chinese Academy of Sciences ; Experimental Technology Innovation Fund of the Institute of Geology and Geophysics, Chinese Academy of Sciences ; Key Research Program of the Chinese Academy of Sciences ; Key Research Program of the Chinese Academy of Sciences ; Key Research Program of the Chinese Academy of Sciences ; Key Research Program of the Chinese Academy of Sciences ; pre-research project on Civil Aerospace Technologies of China National Space Administration ; pre-research project on Civil Aerospace Technologies of China National Space Administration ; pre-research project on Civil Aerospace Technologies of China National Space Administration ; pre-research project on Civil Aerospace Technologies of China National Space Administration ; Key Research Program ; Key Research Program ; Key Research Program ; Key Research Program ; Experimental Technology Innovation Fund of the Institute of Geology and Geophysics, Chinese Academy of Sciences ; Experimental Technology Innovation Fund of the Institute of Geology and Geophysics, Chinese Academy of Sciences ; Experimental Technology Innovation Fund of the Institute of Geology and Geophysics, Chinese Academy of Sciences ; Experimental Technology Innovation Fund of the Institute of Geology and Geophysics, Chinese Academy of Sciences ; Key Research Program of the Chinese Academy of Sciences ; Key Research Program of the Chinese Academy of Sciences ; Key Research Program of the Chinese Academy of Sciences ; Key Research Program of the Chinese Academy of Sciences ; pre-research project on Civil Aerospace Technologies of China National Space Administration ; pre-research project on Civil Aerospace Technologies of China National Space Administration ; pre-research project on Civil Aerospace Technologies of China National Space Administration ; pre-research project on Civil Aerospace Technologies of China National Space Administration ; Key Research Program ; Key Research Program ; Key Research Program ; Key Research Program ; Experimental Technology Innovation Fund of the Institute of Geology and Geophysics, Chinese Academy of Sciences ; Experimental Technology Innovation Fund of the Institute of Geology and Geophysics, Chinese Academy of Sciences ; Experimental Technology Innovation Fund of the Institute of Geology and Geophysics, Chinese Academy of Sciences ; Experimental Technology Innovation Fund of the Institute of Geology and Geophysics, Chinese Academy of Sciences ; Key Research Program of the Chinese Academy of Sciences ; Key Research Program of the Chinese Academy of Sciences ; Key Research Program of the Chinese Academy of Sciences ; Key Research Program of the Chinese Academy of Sciences ; pre-research project on Civil Aerospace Technologies of China National Space Administration ; pre-research project on Civil Aerospace Technologies of China National Space Administration ; pre-research project on Civil Aerospace Technologies of China National Space Administration ; pre-research project on Civil Aerospace Technologies of China National Space Administration ; Key Research Program ; Key Research Program ; Key Research Program ; Key Research Program ; Experimental Technology Innovation Fund of the Institute of Geology and Geophysics, Chinese Academy of Sciences ; Experimental Technology Innovation Fund of the Institute of Geology and Geophysics, Chinese Academy of Sciences ; Experimental Technology Innovation Fund of the Institute of Geology and Geophysics, Chinese Academy of Sciences ; Experimental Technology Innovation Fund of the Institute of Geology and Geophysics, Chinese Academy of Sciences |
| WOS Keyword | COMET 81P/WILD 2 ; MAGNETIC-PROPERTIES ; SHOCK METAMORPHISM ; OPAQUE MINERALS ; IRON SULFIDES ; LUNAR ; METAL ; FE ; IDENTIFICATION ; HEMATITE |
| Language | 英语 |
| Funding Project | Key Research Program of the Chinese Academy of Sciences[ZDBS-SSW-JSC007-15] ; pre-research project on Civil Aerospace Technologies of China National Space Administration[D020203] ; Key Research Program[IGGCAS-202101] ; Experimental Technology Innovation Fund of the Institute of Geology and Geophysics, Chinese Academy of Sciences[E0518504] |
| Funding Organization | Key Research Program of the Chinese Academy of Sciences ; Key Research Program of the Chinese Academy of Sciences ; Key Research Program of the Chinese Academy of Sciences ; Key Research Program of the Chinese Academy of Sciences ; pre-research project on Civil Aerospace Technologies of China National Space Administration ; pre-research project on Civil Aerospace Technologies of China National Space Administration ; pre-research project on Civil Aerospace Technologies of China National Space Administration ; pre-research project on Civil Aerospace Technologies of China National Space Administration ; Key Research Program ; Key Research Program ; Key Research Program ; Key Research Program ; Experimental Technology Innovation Fund of the Institute of Geology and Geophysics, Chinese Academy of Sciences ; Experimental Technology Innovation Fund of the Institute of Geology and Geophysics, Chinese Academy of Sciences ; Experimental Technology Innovation Fund of the Institute of Geology and Geophysics, Chinese Academy of Sciences ; Experimental Technology Innovation Fund of the Institute of Geology and Geophysics, Chinese Academy of Sciences ; Key Research Program of the Chinese Academy of Sciences ; Key Research Program of the Chinese Academy of Sciences ; Key Research Program of the Chinese Academy of Sciences ; Key Research Program of the Chinese Academy of Sciences ; pre-research project on Civil Aerospace Technologies of China National Space Administration ; pre-research project on Civil Aerospace Technologies of China National Space Administration ; pre-research project on Civil Aerospace Technologies of China National Space Administration ; pre-research project on Civil Aerospace Technologies of China National Space Administration ; Key Research Program ; Key Research Program ; Key Research Program ; Key Research Program ; Experimental Technology Innovation Fund of the Institute of Geology and Geophysics, Chinese Academy of Sciences ; Experimental Technology Innovation Fund of the Institute of Geology and Geophysics, Chinese Academy of Sciences ; Experimental Technology Innovation Fund of the Institute of Geology and Geophysics, Chinese Academy of Sciences ; Experimental Technology Innovation Fund of the Institute of Geology and Geophysics, Chinese Academy of Sciences ; Key Research Program of the Chinese Academy of Sciences ; Key Research Program of the Chinese Academy of Sciences ; Key Research Program of the Chinese Academy of Sciences ; Key Research Program of the Chinese Academy of Sciences ; pre-research project on Civil Aerospace Technologies of China National Space Administration ; pre-research project on Civil Aerospace Technologies of China National Space Administration ; pre-research project on Civil Aerospace Technologies of China National Space Administration ; pre-research project on Civil Aerospace Technologies of China National Space Administration ; Key Research Program ; Key Research Program ; Key Research Program ; Key Research Program ; Experimental Technology Innovation Fund of the Institute of Geology and Geophysics, Chinese Academy of Sciences ; Experimental Technology Innovation Fund of the Institute of Geology and Geophysics, Chinese Academy of Sciences ; Experimental Technology Innovation Fund of the Institute of Geology and Geophysics, Chinese Academy of Sciences ; Experimental Technology Innovation Fund of the Institute of Geology and Geophysics, Chinese Academy of Sciences ; Key Research Program of the Chinese Academy of Sciences ; Key Research Program of the Chinese Academy of Sciences ; Key Research Program of the Chinese Academy of Sciences ; Key Research Program of the Chinese Academy of Sciences ; pre-research project on Civil Aerospace Technologies of China National Space Administration ; pre-research project on Civil Aerospace Technologies of China National Space Administration ; pre-research project on Civil Aerospace Technologies of China National Space Administration ; pre-research project on Civil Aerospace Technologies of China National Space Administration ; Key Research Program ; Key Research Program ; Key Research Program ; Key Research Program ; Experimental Technology Innovation Fund of the Institute of Geology and Geophysics, Chinese Academy of Sciences ; Experimental Technology Innovation Fund of the Institute of Geology and Geophysics, Chinese Academy of Sciences ; Experimental Technology Innovation Fund of the Institute of Geology and Geophysics, Chinese Academy of Sciences ; Experimental Technology Innovation Fund of the Institute of Geology and Geophysics, Chinese Academy of Sciences |
| WOS Research Area | Astronomy & Astrophysics |
| WOS Subject | Astronomy & Astrophysics |
| WOS ID | WOS:000872598000001 |
| Publisher | ACADEMIC PRESS INC ELSEVIER SCIENCE |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.iggcas.ac.cn/handle/132A11/107747 |
| Collection | 岩石圈演化国家重点实验室 地球与行星物理院重点实验室 |
| Corresponding Author | Chen, Yi |
| Affiliation | 1.Chinese Acad Sci, Inst Geol & Geophys, State Key Lab Lithospher Evolut, Beijing 100029, Peoples R China 2.Chinese Acad Sci, Inst Geol & Geophys, Electron Microscope Lab, Beijing 100029, Peoples R China 3.Chinese Acad Sci, Inst Geol & Geophys, Key Lab Earth & Planetary Phys, Beijing 100029, Peoples R China 4.Chinese Acad Sci, Inst Phys, Beijing Natl Lab Condensed Matter Phys, Beijing 100190, Peoples R China 5.Penn State Univ, Dept Ecosyst Sci & Management, University Pk, PA 16802 USA 6.Penn State Univ, Mat Res Inst, Energy & Environm Lab 204, University Pk, PA 16802 USA |
| First Author Affilication | State Key Laboratory of Lithospheric Evolution |
| Corresponding Author Affilication | State Key Laboratory of Lithospheric Evolution |
| Recommended Citation GB/T 7714 | Li, Xiaoguang,Chen, Yi,Tang, Xu,et al. Thermally induced phase transition of troilite during Micro-Raman spectroscopy analysis[J]. ICARUS,2023,390:10. |
| APA | Li, Xiaoguang.,Chen, Yi.,Tang, Xu.,Gu, Lixin.,Yuan, Jiangyan.,...&Komarneni, Sridhar.(2023).Thermally induced phase transition of troilite during Micro-Raman spectroscopy analysis.ICARUS,390,10. |
| MLA | Li, Xiaoguang,et al."Thermally induced phase transition of troilite during Micro-Raman spectroscopy analysis".ICARUS 390(2023):10. |
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