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The study of Early Mesoproterozoic variegated shales in the southern North China Craton and its paleoenvironmental implications
Zuo PengFei1,2; Zhu XiYan3; Zheng DeShun1; Sun FengBo1; Wang ShiYan4
2022-06-01
Source PublicationACTA PETROLOGICA SINICA
ISSN1000-0569
Volume38Issue:6Pages:1713-1726
AbstractThe evolution of oxygen-increasing is one of the most significant events in the history of the Earth. It is controversial if there are variable oxygen levels in Proterozoic. Fine-grained sedimentary rocks, which record the redox state of the ocean sensitively, can be used in constraining the oxygen levels. A series of shales in the North China Craton ( NCC ) were deposited in extension environments after 1800Ma. Variegated shales, from the black shales in a shelf-neritic environment ( ca. 1648Ma) , were carried out in mineralogy and geochemistry study. Scanning electron microscope and X-ray diffraction ( XRD) show purplish-red and dark-green flaky shales mainly consist of illite, quartz and K-feldspar. Hematite distributes in biotite and chlorite and indicates its alteration genesis. Illite occurs as fibrous within intergranular pore among detrital K-feldspar, quartz and muscovite. Illite consists of 1M polytype suggesting very low- to low-grade metamorphism. The Chemical Index of Alteration ( CIA) indicates intense weathering during the deposition of the shales. Compared with Post-Archean Australian Shales ( PAAS) , there is a slight enrichment in HREE, depletion in LREE and positive Eu anomalies. It is noted that enrichment of total iron has not been observed in the shales more than that of the PAAS and North America Shales ( NASC) and, by extension, implying no anoxia. Transition trace elements ( V, Cr, Co and Ni) show oxidized water column. It is reasonable to infer that neritic-shelf seawater has been oxidized in combination with a stratified model of the Mesoproterozoic Ocean. Meanwhile, contemporaneous clay and shale deposits also indicate intense weathering worldwide and it could be related to variable oxygen contents.
KeywordBlack shales North China Craton Mesoproterozoic Oxygenation event
DOI10.18654/1000-0569/2022.06.11
WOS KeywordGEOCHEMISTRY
Language英语
WOS Research AreaGeology
WOS SubjectGeology
WOS IDWOS:000826244200011
PublisherSCIENCE PRESS
Citation statistics
Document Type期刊论文
Identifierhttp://ir.iggcas.ac.cn/handle/132A11/108461
Collection矿产资源研究院重点实验室
Corresponding AuthorZuo PengFei
Affiliation1.Henan Polytech Univ, Sch Resources & Environm, Jiaozuo 454000, Henan, Peoples R China
2.China Univ Geosci, State Key Lab Geol Proc & Mineral Resources, Beijing 100083, Peoples R China
3.Chinese Acad Sci, Inst Geol & Geophys, Key Lab Mineral Resources, Beijing 100029, Peoples R China
4.Henan Inst Geol Survey, Zhengzhou 450001, Peoples R China
Recommended Citation
GB/T 7714
Zuo PengFei,Zhu XiYan,Zheng DeShun,et al. The study of Early Mesoproterozoic variegated shales in the southern North China Craton and its paleoenvironmental implications[J]. ACTA PETROLOGICA SINICA,2022,38(6):1713-1726.
APA Zuo PengFei,Zhu XiYan,Zheng DeShun,Sun FengBo,&Wang ShiYan.(2022).The study of Early Mesoproterozoic variegated shales in the southern North China Craton and its paleoenvironmental implications.ACTA PETROLOGICA SINICA,38(6),1713-1726.
MLA Zuo PengFei,et al."The study of Early Mesoproterozoic variegated shales in the southern North China Craton and its paleoenvironmental implications".ACTA PETROLOGICA SINICA 38.6(2022):1713-1726.
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