Hydrogen bonding in goldichite, KFe(SO4)(2)center dot 4H(2)O: structure refinement

doi:10.1007/s00710-017-0524-0

IGGCAS OpenIR

	Hydrogen bonding in goldichite, KFe(SO4)(2)center dot 4H(2)O: structure refinement
	Yang, Zhuming 1,2; Giester, Gerald 3
	2018-02-01
发表期刊	MINERALOGY AND PETROLOGY
ISSN	0930-0708
卷号	112 期号:1 页码:135-142
文章类型	Article
摘要	The crystal structure of goldichite KFe(SO4)(2)ai...4H(2)O was determined on a single crystal from the Baiyinchang copper deposit, Gansu, China. [P12(1)/c1, a = 10.395(2), b = 10.475(2), c = 9.0875(18) , beta = 101.65(3)A degrees, V = 969.1(3) (3), Z = 4]. All non-H atoms were refined with anisotropic displacement parameters and positions of H-atoms were determined by difference Fourier methods and refined from X-ray diffraction data. The crystal structure of goldichite consists of corrugated sheets parallel to the (100) plane by sharing corners between FeO6 octahedra and SO4 tetrahedra. The interstitial potassium atom exhibits a [KO7(H2O)(2)] nine-fold coordination, which shares edges to form a column parallel to the c-axis and to build a slab with the corrugated sheet. These slabs are linked in the [100] direction through a network of hydrogen bonds. Three types of hydrogen bonds involve links of slabs: O-w(3)-H(3B)center dot center dot center dot O(1), O-w(6)-H(6B)center dot center dot center dot O(11) and O-w(9)-H(9B)center dot center dot center dot O(11). The FTIR spectrum of goldichite shows a strong absorption between similar to 3384 cm(-1) and similar to 3592 cm(-1), which is in accordance with the O-H center dot center dot center dot O distances derived from structure data.
关键词	Goldichite Hydrogen Bonding Hydrated Sulfate Crystal Structure Oxidation Zone Of Copper Deposit
WOS标题词	Science & Technology ; Physical Sciences
DOI	10.1007/s00710-017-0524-0
资助者	National Natural Science Foundation of China(41272063) ; National Natural Science Foundation of China(41272063) ; National Natural Science Foundation of China(41272063) ; National Natural Science Foundation of China(41272063) ; National Natural Science Foundation of China(41272063) ; National Natural Science Foundation of China(41272063) ; National Natural Science Foundation of China(41272063) ; National Natural Science Foundation of China(41272063) ; National Natural Science Foundation of China(41272063) ; National Natural Science Foundation of China(41272063) ; National Natural Science Foundation of China(41272063) ; National Natural Science Foundation of China(41272063) ; National Natural Science Foundation of China(41272063) ; National Natural Science Foundation of China(41272063) ; National Natural Science Foundation of China(41272063) ; National Natural Science Foundation of China(41272063)
关键词[WOS]	MINERALS ; SULFATE ; VALENCE
收录类别	SCI
语种	英语
资助者	National Natural Science Foundation of China(41272063) ; National Natural Science Foundation of China(41272063) ; National Natural Science Foundation of China(41272063) ; National Natural Science Foundation of China(41272063) ; National Natural Science Foundation of China(41272063) ; National Natural Science Foundation of China(41272063) ; National Natural Science Foundation of China(41272063) ; National Natural Science Foundation of China(41272063) ; National Natural Science Foundation of China(41272063) ; National Natural Science Foundation of China(41272063) ; National Natural Science Foundation of China(41272063) ; National Natural Science Foundation of China(41272063) ; National Natural Science Foundation of China(41272063) ; National Natural Science Foundation of China(41272063) ; National Natural Science Foundation of China(41272063) ; National Natural Science Foundation of China(41272063)
WOS研究方向	Geochemistry & Geophysics ; Mineralogy
WOS类目	Geochemistry & Geophysics ; Mineralogy
WOS记录号	WOS:000423699000009
出版者	SPRINGER WIEN
引用统计
文献类型	期刊论文
条目标识符	http://ir.iggcas.ac.cn/handle/132A11/82627
专题	中国科学院地质与地球物理研究所
通讯作者	Giester, Gerald
作者单位	1.Chinese Acad Sci, Inst Geol & Geophys, Beijing 100029, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 3.Univ Wien, Inst Mineral & Kristallog, Althanstr 14, A-1090 Vienna, Austria
第一作者单位	中国科学院地质与地球物理研究所
推荐引用方式 GB/T 7714	Yang, Zhuming,Giester, Gerald. Hydrogen bonding in goldichite, KFe(SO4)(2)center dot 4H(2)O: structure refinement[J]. MINERALOGY AND PETROLOGY,2018,112(1):135-142.
APA	Yang, Zhuming,&Giester, Gerald.(2018).Hydrogen bonding in goldichite, KFe(SO4)(2)center dot 4H(2)O: structure refinement.MINERALOGY AND PETROLOGY,112(1),135-142.
MLA	Yang, Zhuming,et al."Hydrogen bonding in goldichite, KFe(SO4)(2)center dot 4H(2)O: structure refinement".MINERALOGY AND PETROLOGY 112.1(2018):135-142.