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Raman and infrared spectra to monitor the phase transition of natural kyanite under static compression
Gao, Jing1,2; Wu, Wanghua3; Jia, Lihui1,2; Wang, Ching-Pao4; Liu, Yingxin5; Xu, Chaowen6; Chen, Fei1,2; Fei, Chenhui1,2; Su, Wen1,2
2020-07-27
Source PublicationJOURNAL OF RAMAN SPECTROSCOPY
ISSN0377-0486
Pages10
AbstractThe stability of kyanite Al2SiO5 at high pressure is of significance in understanding the fate of the subducted crust and how they recycle within the Earth. Thus, in situ high-pressure vibrational spectra of natural kyanite are presented. The shift amplitudes of the measured modes dependent on pressure manifest the contraction of the Al-O bond bears the most compression of kyanite. At 9.7 GPa, a first-order phase transition to kyanite-II occurs, which is distinguished by changes occurred in the entire spectral region, including the pressure dependences of the modes, the wavenumber jumps of some peaks, the splitting of a Si-O symmetric stretching band, and the emergence of new modes. A Raman mapping image is collected illustrating kyanite and kyanite-II in coexistence at 10.0 GPa. Emphasize that, as is revealed by the infrared spectra, a part of H-O center dot center dot center dot O distance becomes elongated after the transformation. At higher pressure up to 18.6 GPa, the Raman spectra disclose little effects associated with further transformations. Finally, releasing pressure to ambient leads to recovery of pure kyanite. Our results mark a lowest pressure limit of the change in the intermolecular and intramolecular bonding of kyanite and shed new lights on the crystal chemistry of aluminosilicate under mantle pressures.
Keywordaluminosilicate crystal chemistry diamond anvil cell kyanite phase transition Raman mapping
DOI10.1002/jrs.5954
Funding OrganizationChina Postdoctoral Science Foundation ; China Postdoctoral Science Foundation ; China Postdoctoral Science Foundation ; China Postdoctoral Science Foundation ; Natural Science Foundation of China ; Natural Science Foundation of China ; Natural Science Foundation of China ; Natural Science Foundation of China ; Open Foundation of the United Laboratory of High-Pressure Physics and Earthquake Science ; Open Foundation of the United Laboratory of High-Pressure Physics and Earthquake Science ; Open Foundation of the United Laboratory of High-Pressure Physics and Earthquake Science ; Open Foundation of the United Laboratory of High-Pressure Physics and Earthquake Science ; National Key Research and Development Program of China ; National Key Research and Development Program of China ; National Key Research and Development Program of China ; National Key Research and Development Program of China ; China Postdoctoral Science Foundation ; China Postdoctoral Science Foundation ; China Postdoctoral Science Foundation ; China Postdoctoral Science Foundation ; Natural Science Foundation of China ; Natural Science Foundation of China ; Natural Science Foundation of China ; Natural Science Foundation of China ; Open Foundation of the United Laboratory of High-Pressure Physics and Earthquake Science ; Open Foundation of the United Laboratory of High-Pressure Physics and Earthquake Science ; Open Foundation of the United Laboratory of High-Pressure Physics and Earthquake Science ; Open Foundation of the United Laboratory of High-Pressure Physics and Earthquake Science ; National Key Research and Development Program of China ; National Key Research and Development Program of China ; National Key Research and Development Program of China ; National Key Research and Development Program of China ; China Postdoctoral Science Foundation ; China Postdoctoral Science Foundation ; China Postdoctoral Science Foundation ; China Postdoctoral Science Foundation ; Natural Science Foundation of China ; Natural Science Foundation of China ; Natural Science Foundation of China ; Natural Science Foundation of China ; Open Foundation of the United Laboratory of High-Pressure Physics and Earthquake Science ; Open Foundation of the United Laboratory of High-Pressure Physics and Earthquake Science ; Open Foundation of the United Laboratory of High-Pressure Physics and Earthquake Science ; Open Foundation of the United Laboratory of High-Pressure Physics and Earthquake Science ; National Key Research and Development Program of China ; National Key Research and Development Program of China ; National Key Research and Development Program of China ; National Key Research and Development Program of China ; China Postdoctoral Science Foundation ; China Postdoctoral Science Foundation ; China Postdoctoral Science Foundation ; China Postdoctoral Science Foundation ; Natural Science Foundation of China ; Natural Science Foundation of China ; Natural Science Foundation of China ; Natural Science Foundation of China ; Open Foundation of the United Laboratory of High-Pressure Physics and Earthquake Science ; Open Foundation of the United Laboratory of High-Pressure Physics and Earthquake Science ; Open Foundation of the United Laboratory of High-Pressure Physics and Earthquake Science ; Open Foundation of the United Laboratory of High-Pressure Physics and Earthquake Science ; National Key Research and Development Program of China ; National Key Research and Development Program of China ; National Key Research and Development Program of China ; National Key Research and Development Program of China
WOS KeywordHIGH-PRESSURE BEHAVIOR ; AL2SIO5 POLYMORPHS ; CRYSTAL-STRUCTURE ; POSSIBLE HOST ; SILLIMANITE ; ANDALUSITE ; TEMPERATURE ; ALUMINUM ; DECOMPOSITION ; CALIBRATION
Language英语
Funding ProjectChina Postdoctoral Science Foundation[2018M640179] ; China Postdoctoral Science Foundation[2019T120132] ; Natural Science Foundation of China[1902035] ; Natural Science Foundation of China[41490614] ; Natural Science Foundation of China[41822202] ; Natural Science Foundation of China[41902035] ; Open Foundation of the United Laboratory of High-Pressure Physics and Earthquake Science[2019HPPES07] ; National Key Research and Development Program of China[2018YFA 0702601]
Funding OrganizationChina Postdoctoral Science Foundation ; China Postdoctoral Science Foundation ; China Postdoctoral Science Foundation ; China Postdoctoral Science Foundation ; Natural Science Foundation of China ; Natural Science Foundation of China ; Natural Science Foundation of China ; Natural Science Foundation of China ; Open Foundation of the United Laboratory of High-Pressure Physics and Earthquake Science ; Open Foundation of the United Laboratory of High-Pressure Physics and Earthquake Science ; Open Foundation of the United Laboratory of High-Pressure Physics and Earthquake Science ; Open Foundation of the United Laboratory of High-Pressure Physics and Earthquake Science ; National Key Research and Development Program of China ; National Key Research and Development Program of China ; National Key Research and Development Program of China ; National Key Research and Development Program of China ; China Postdoctoral Science Foundation ; China Postdoctoral Science Foundation ; China Postdoctoral Science Foundation ; China Postdoctoral Science Foundation ; Natural Science Foundation of China ; Natural Science Foundation of China ; Natural Science Foundation of China ; Natural Science Foundation of China ; Open Foundation of the United Laboratory of High-Pressure Physics and Earthquake Science ; Open Foundation of the United Laboratory of High-Pressure Physics and Earthquake Science ; Open Foundation of the United Laboratory of High-Pressure Physics and Earthquake Science ; Open Foundation of the United Laboratory of High-Pressure Physics and Earthquake Science ; National Key Research and Development Program of China ; National Key Research and Development Program of China ; National Key Research and Development Program of China ; National Key Research and Development Program of China ; China Postdoctoral Science Foundation ; China Postdoctoral Science Foundation ; China Postdoctoral Science Foundation ; China Postdoctoral Science Foundation ; Natural Science Foundation of China ; Natural Science Foundation of China ; Natural Science Foundation of China ; Natural Science Foundation of China ; Open Foundation of the United Laboratory of High-Pressure Physics and Earthquake Science ; Open Foundation of the United Laboratory of High-Pressure Physics and Earthquake Science ; Open Foundation of the United Laboratory of High-Pressure Physics and Earthquake Science ; Open Foundation of the United Laboratory of High-Pressure Physics and Earthquake Science ; National Key Research and Development Program of China ; National Key Research and Development Program of China ; National Key Research and Development Program of China ; National Key Research and Development Program of China ; China Postdoctoral Science Foundation ; China Postdoctoral Science Foundation ; China Postdoctoral Science Foundation ; China Postdoctoral Science Foundation ; Natural Science Foundation of China ; Natural Science Foundation of China ; Natural Science Foundation of China ; Natural Science Foundation of China ; Open Foundation of the United Laboratory of High-Pressure Physics and Earthquake Science ; Open Foundation of the United Laboratory of High-Pressure Physics and Earthquake Science ; Open Foundation of the United Laboratory of High-Pressure Physics and Earthquake Science ; Open Foundation of the United Laboratory of High-Pressure Physics and Earthquake Science ; National Key Research and Development Program of China ; National Key Research and Development Program of China ; National Key Research and Development Program of China ; National Key Research and Development Program of China
WOS Research AreaSpectroscopy
WOS SubjectSpectroscopy
WOS IDWOS:000552462500001
PublisherWILEY
Citation statistics
Document Type期刊论文
Identifierhttp://ir.iggcas.ac.cn/handle/132A11/97569
Collection岩石圈演化国家重点实验室
Corresponding AuthorGao, Jing
Affiliation1.Chinese Acad Sci, Inst Geol & Geophys, State Key Lab Lithospher Evolut, Beijing 100029, Peoples R China
2.Chinese Acad Sci, Inst Geol & Geophys, Inst Earth Sci, Beijing 100029, Peoples R China
3.WITec Beijing Sci Technol Co Ltd, Unit 507,Landmark Tower 1,8 North Dongsanhuan Rd, Beijing 100004, Peoples R China
4.Univ Western Ontario, Dept Earth Sci, London, ON N6A 5B7, Canada
5.China Univ Geosci, Sch Gemmol, Beijing 100083, Peoples R China
6.China Earthquake Adm, United Lab High Pressure Phys & Earthquake Sci, Inst Earthquake Forecasting, Beijing 100036, Peoples R China
First Author AffilicationState Key Laboratory of Lithospheric Evolution;  Institute of Geology and Geophysics, Chinese Academy of Sciences
Corresponding Author AffilicationState Key Laboratory of Lithospheric Evolution;  Institute of Geology and Geophysics, Chinese Academy of Sciences
Recommended Citation
GB/T 7714
Gao, Jing,Wu, Wanghua,Jia, Lihui,et al. Raman and infrared spectra to monitor the phase transition of natural kyanite under static compression[J]. JOURNAL OF RAMAN SPECTROSCOPY,2020:10.
APA Gao, Jing.,Wu, Wanghua.,Jia, Lihui.,Wang, Ching-Pao.,Liu, Yingxin.,...&Su, Wen.(2020).Raman and infrared spectra to monitor the phase transition of natural kyanite under static compression.JOURNAL OF RAMAN SPECTROSCOPY,10.
MLA Gao, Jing,et al."Raman and infrared spectra to monitor the phase transition of natural kyanite under static compression".JOURNAL OF RAMAN SPECTROSCOPY (2020):10.
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